千葉大学大学院理学研究科基盤理学専攻化学コース
遷移金属触媒有機化学研究室

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Papers


2024

1)
Synthesis of [1]Benzothieno[3,2-b][1]benzothiophenes through Iodine-Mediated Sulfur Insertion Reaction
Chem. Eur. J. 2024, 30, online.
Kazuki Ito, Kohei Nakamura, and Kazuhiro Yoshida


2023

1)
Synthesis of [1]Benzothieno[2,3-b][1]benzothiophenes from 3-Arylbenzo[b]thiophenes through Iodine-Mediated Sulfur Insertion Reaction
J. Org. Chem. 2023, 88, 14797-14802.
Kazuki Ito, Shuta Sakai, and Kazuhiro Yoshida


2022

1)
Facile One-Pot Preparation of 5-Substituted 4-Iodo-1-tosylpyrazoles from N-Propargyl-N'-tosylhydrazines through Iodocyclization
Synthesis 2022, 54, 3114-3124.
Aya Saito, Kazuhiro Yoshida, and Hideo Togo

2)
Novel Preparation of 2,5-Diarylpyrroles from Aromatic Nitriles with 3-Arylpropylmagnesium Bromides, 1,3-Diiodo-5,5-dimethylhydantoin, and tBuOK
Tetrahedron 2022, 111, 132709.
Momoko Nakamura, Kazuhiro Yoshida, and Hideo Togo

3)

Chiral Bicyclic NHC/Rh Complexes and Their Application to Catalytic Asymmetric Ring-Opening Reaction of Oxabenzonorbornadienes with Amines
J. Org. Chem. 2022, 87, 3007-3013.
Mizuki Seki and Kazuhiro Yoshida



2021

1)
Enantioselective Desymmetrization of 1,3-Disubstituted Adamantane Derivatives via Rhodium-Catalyzed C-H Bond Amination: Access to Optically Active Amino Acids Containing Adamantane Core
Adv. Synth. Catal. 2021, 363, 1662-1671 (selected as a VIP).
Risa Yasue and Kazuhiro Yoshida


2020

1)
Oxidative Cyclization of o-(1-Hydroxy-2-alkynyl)-N-tosylanilides for Synthesis of 4-Quinolones
J. Org. Chem. 2020, 85, 6420-6428.
Jun-ichi Ueda, Yuuki Enomoto, Mizuki Seki, Takuma Konishi, Masamichi Ogasawara, and Kazuhiro Yoshida

2)
N-Heterocyclic Carbene Ligands Having Planar Chiral Ferrocene Structure
J. Synth. Org. Chem., Jpn. 2020, 78, 28-40 (Review).
Kazuhiro Yoshida and Risa Yasue

3)
Development of Planar Chiral Five-membered Cyclic (Amino)(ferrocenylene)carbene Ligand and Its Iridium Dicarbonyl Complex
Bull. Chem. Soc. Jpn. 2020, 93, 200-204.
Waka Takagaki, Risa Yasue, and Kazuhiro Yoshida

4)
Synthesis of [1]Benzothiopheno[2,3-b][1]benzothiophene Derivatives through Iodine-mediated Sulfuration Reaction of 1,1-Diarylethylenes
Tetrahedron Lett. 2020, 61, 151476.
Shuta Sakai, Kazuki Sato, and Kazuhiro Yoshida


5)
Versatile and Enantioselective Preparation of Planar-Chiral Metallocene-Fused 4-Dialkylaminopyridines and Their Application in Asymmetric Organocatalysis
ACS Catal. 2020, 10, 292-301.
Kazuhiro Yoshida, Qiang Liu, Risa Yasue, Shiro Wada, Ryosuke Kimura, Takuma Konishi, and Masamichi Ogasawara



2019

1)
Chiral Bicyclic NHC/Cu Complexes for Catalytic Asymmetric Borylation of α,β-Unsaturated Esters
J. Org. Chem. 2019, 84, 14291-14296.
Yuya Miwa, Takumi Kamimura, Kiyoaki Sato, Daichi Shishido, and Kazuhiro Yoshida

2)
Synthesis and Application of Planar Chiral Cyclic (Amino)(ferrocenyl)carbene Ligands Bearing FeCp* Group
Organometallics 2019, 38, 2211-2217.
Risa Yasue and Kazuhiro Yoshida



2018

1)
Planar-Chiral Ferrocene-Based N-Heterocyclic Carbene Ligands
Chem. Eur. J. 2018, 24, 18575-18586 (Review) (Top Downloaded Paper 2018-2019).
Kazuhiro Yoshida and Risa Yasue



2017

1)
Coordination Behavior of a Planar Chiral Cyclic (Amino)(Ferrocenyl)Carbene Ligand in Iridium Complexes
Chem. Eur. J. 2017, 23, 16806-16812 (Hot Paper).
Yuta Shikata, Risa Yasue, and Kazuhiro Yoshida

2)
A Planar Chiral Six-Membered Cyclic (Amino)(Ferrocenyl)Carbene and Its Sulfur Adduct
Tetrahedron: Asymmetry 2017, 28, 824-829.
Risa Yasue, Masaru Miyauchi, and Kazuhiro Yoshida

3)
Synthesis of o-Allyloxyethynylbenzene Derivatives via Cu-Catalyzed Suzuki-Miyaura-Type Reaction and Their Transformations for Heterocyclic Compounds
Eur. J. Org. Chem. 2017, 2359-2368.
Kohei Watanabe, Takashi Mino, Eri Ishikawa, Miyu Okano, Tatsuya Ikematsu, Yasushi Yoshida, Masami Sakamoto, Kazuki Sato, and Kazuhiro Yoshida

4)
Planar Chiral Cyclic (Amino)(ferrocenyl)carbene as Ligand for Transition Metals
Adv. Synth. Catal. 2017, 359, 255-259.
Risa Yasue, Masaru Miyauchi, and Kazuhiro Yoshida

5)
Enantioselective Synthesis of Ferrocene- or Cymantrene-Fused Planar-Chiral Phospholes
Eur. J. Inorg. Chem. 2017, 325-329.
Hao Hu, Wei-Yi Wu, Tamotsu Takahashi, Kazuhiro Yoshida, and Masamichi Ogasawara



2016

1)
Enantioselective Nitroso Aldol Reaction Catalyzed by Chiral Phosphine-Silver Complex
Eur. J. Org. Chem. 2016, 5355-5359.
Akira Yanagisawa, Yuqin Lin, Akihiro Takeishi, and Kazuhiro Yoshida

2)
Enantio- and Diastereoselective Cross-Annulation of Enal and Ketone with New Chiral Bicyclic N-Heterocyclic Carbene Catalysts
Chem. Lett. 2016, 45, 294-296.
Momo Hasegawa, Kazuhiro Yoshida, and Akira Yanagisawa


2015


1)
Catalytic Enantioselective Synthesis of Chiral 3-Amino-2-oxindoles by a Mannich Approach
Synlett 2015, 26, 2541-2546.
Akira Yanagisawa, Naoyuki Kushihara, Takuya Sugita, Moe Horiguchi, Kazuki Ida, and Kazuhiro Yoshida

2)
Chiral Bicyclic NHC/Ir Complexes for Catalytic Asymmetric Transfer Hydrogenation of Ketones
Chem. Commun. 2015, 51, 15442-15445. 
Kazuhiro Yoshida, Takumi Kamimura, Hiroshi Kuwabara, and Akira Yanagisawa


3)
Utilization of Optically Active Secondary Phosphine-Boranes: Synthesis of P-chiral Diphosphines and Their Enantioinduction Ability in Rhodium-catalyzed Asymmetric Hydrogenation
Tetrahedron 2015, 71, 6471-6480. 
Tsuneo Imamoto, Yumi Horiuchi, Eri Hamanishi, Satoshi Takeshita, Ken Tamura, Masashi Sugiya, and Kazuhiro Yoshida


4)
Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library
Org. Lett. 2015, 17, 2286-2289. 
Masamichi Ogasawara, Shiro Wada, Erika Isshiki, Takumi Kamimura, Akira Yanagisawa, Tamotsu Takahashi, and Kazuhiro Yoshida

5)
Reactive Barium-Promoted Benzylation of Diaryl Azo Compounds
Synlett
2015, 26, 1073-1076. 
Akira Yanagisawa, Toshiki Sawae, Seiya Yamafuji, Toshihiko Heima, and Kazuhiro Yoshida



2014


1)
Asymmetric Aldol Reaction Catalyzed by a Chiral Phosphine-Silver Complex
Eur. J. Org. Chem. 2014, 4248-4253. 
Akira Yanagisawa, Ryoji Miyake, and Kazuhiro Yoshida


2)
Synthesis of Substituted Styrenes and 3-Vinylphenols Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis
J. Org. Chem. 2014, 79, 4231-4239. 
Kazuhiro Yoshida, Kana Nishii, Yuto Kano, Shiro Wada, and Akira Yanagisawa

3)
Catalytic Enantioselective Mannich-Type Reaction via a Chiral Silver Enolate
Org. Lett. 2014, 16, 86-89. 
Akira Yanagisawa, Yuqin Lin, Ryoji Miyake, and Kazuhiro Yoshida

4)
Asymmetric α-Amination Reaction of Alkenyl Trifluoroacetates Catalyzed by Chiral Phosphine-Silver Complex
Org. Biomol. Chem.
2014, 12, 1935-1941. 
Akira Yanagisawa, Ryoji Miyake, and Kazuhiro Yoshida



2013

1)
Enantioselective Protonation of Alkenyl Trifluoroacetates Catalyzed by Chiral Tin Methoxide: A New
Entry to Optically Active Ketones

Chem. Eur. J. 2013, 19, 16200-16203. 
Akira Yanagisawa, Takuya Sugita, and Kazuhiro Yoshida

2)
Synthesis of 4-Vinylindoles Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis
J. Org. Chem. 2013, 78, 3464-3469. 
Kazushi Hayashi, Kazuhiro Yoshida, and Akira Yanagisawa

3)
α-Selective Allylation of Azo Compounds Using Allylic Barium Reagents
Synlett
2013, 24, 635-639. 
Akira Yanagisawa, Takuya Jitsukawa, and Kazuhiro Yoshida

4)
Development of Asymmetric Reactions Catalyzed by Chiral Organotin-Alkoxide Reagents
Chem. Rec.
2013, 13, 117-127. 
Akira Yanagisawa and Kazuhiro Yoshida




Patents


1)
4-ピリドンおよびその製造方法
特願 2015-206798
吉田 和弘小笠原 正道和田 志郎劉 強木村亮介 (千葉大学)

2)
面性不斉メタロセン縮環カルベン及びその製造方法、並びに該誘導体を配位子とする金属錯体
特願 2016-166374
吉田 和弘安江 里紗宮内 大四方 祐太 (千葉大学)




Books


1)
Yoshida, K. Metathesis Reactions. In Transition-Metal-Mediated Aromatic Ring Construction; Tanaka, K. Ed.; Wiley: Hoboken, NJ, 2013; p 721-742.






Bulletins


1)
吉田 和弘, 面不斉アミノメタロセニルカルベン金属錯体触媒の開発, News Letter Vol. 36 「高難度物質変換反応の開発を指向した精密制御反応場の創出」, p 3-4 (2018).


2)
吉田 和弘, 面性不斉NHC配位子/金属錯体触媒の開発, 千葉大学理学部ニュース, No. 46 (2018).


3)
吉田 和弘, 新たな有機合成手法の開発を目指して, 千葉大学理学部ニュース, No. 33 (2014).

4)
吉田 和弘, 置換芳香族化合物の実践的合成, 千葉大学理学部ニュース, No. 15 (2008).



Commentaries


1)
吉田 和弘,アリールクロリドの酸化的付加に関する新展開:ヘテロバイメタリック錯体の利用,Organometallic News, 99 (2014).